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Which of the following cannot give iodometric titrations

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Which of the following cannot give iodometric titrations

A
Fe3+
B
Cu2+
C
Pb2+
D
Ag+
Answer:

The correct option is C. Pb2+

Note
Atom in highest oxidation state can oxidize iodide to liberate I2 which is volumetrically measured by iodometric titration using hypo. 2I– →I2 Pb+2 → Lowest oxidation state cannot oxidise iodide to I2

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